1,3,4,6-四硫雜戊搭烯-2,5-二酮

1,3,4,6-四硫雜戊搭烯-2,5-二酮
識別
CAS號	64394-45-2
PubChem	555056
ChemSpider	482683
SMILES	C12=C(SC(=O)S1)SC(=O)S2;
性質
化學式	C4O2S4
摩爾質量	208.3 g·mol−1
密度	2 g/cm3
結構
晶體結構	單斜晶系
空間群	P21/c
晶格常數	a = 3.9321(8) Å, b = 10.886(2) Å, c = 8.3000(9) Å
晶格常數	α = 90°, β = 103.60(1)°, γ = 90°
分子構型	D2h
偶極矩	0 D
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

1,3,4,6-四硫雜戊搭烯-2,5-二酮是一種有機化合物，化學式為C₄O₂S₄。它可以和三硫化二硼反應，在甲苯回流生成生成1,3,4,6-四硫雜戊搭烯-2-酮-5-硫酮，固體加熱生成1,3,4,6-四硫雜戊搭烯-2,5-二硫酮。^[2]它和二羰基五甲基環戊二烯基鈷反應，可以得到脫羰基配體的有機鈷衍生物。^[3]

參考文獻

^ ^1.0 ^1.1 Müller, H.; Averbuch, M.-T. 1,3,4,6-Tetrathiapentalene-2,5-dione. Acta Crystallographica Section C Crystal Structure Communications. 1999, 55 (4): 590–592. doi:10.1107/S0108270198014346.
^ Schumaker, R. R.; Engler, E. M. Thiapen chemistry. 2. Synthesis of 1,3,4,6-tetrathiapentalene-2,5-dione. Journal of the American Chemical Society (American Chemical Society (ACS)). 1977, 99 (16): 5521–5522. ISSN 0002-7863. doi:10.1021/ja00458a068.
^ Guyon, Fabrice; Jourdain, Isabelle V.; Knorr, Michael; Lucas, Dominique; Monzon, Theresa; Mugnier, Yves; Avarvari, Narcis; Fourmigué, Marc. Synthesis of μ-C2S44− Cobalt Complexes by Activation of the 1,3,4,6-tetrathiapentalene-2,5-dione, and Electrochemical Study of [(Cp*Co)2(μ-C2S4)]. European Journal of Inorganic Chemistry (Wiley). 2002, 2002 (8): 2026–2033. ISSN 1434-1948. doi:10.1002/1099-0682(200208)2002:8<2026::aid-ejic2026>3.0.co;2-0.

[str-1] 1.0 ^1.1 Müller, H.; Averbuch, M.-T. 1,3,4,6-Tetrathiapentalene-2,5-dione. Acta Crystallographica Section C Crystal Structure Communications. 1999, 55 (4): 590–592. doi:10.1107/S0108270198014346.

[2] Schumaker, R. R.; Engler, E. M. Thiapen chemistry. 2. Synthesis of 1,3,4,6-tetrathiapentalene-2,5-dione. Journal of the American Chemical Society (American Chemical Society (ACS)). 1977, 99 (16): 5521–5522. ISSN 0002-7863. doi:10.1021/ja00458a068.

[3] Guyon, Fabrice; Jourdain, Isabelle V.; Knorr, Michael; Lucas, Dominique; Monzon, Theresa; Mugnier, Yves; Avarvari, Narcis; Fourmigué, Marc. Synthesis of μ-C2S44− Cobalt Complexes by Activation of the 1,3,4,6-tetrathiapentalene-2,5-dione, and Electrochemical Study of [(Cp*Co)2(μ-C2S4)]. European Journal of Inorganic Chemistry (Wiley). 2002, 2002 (8): 2026–2033. ISSN 1434-1948. doi:10.1002/1099-0682(200208)2002:8<2026::aid-ejic2026>3.0.co;2-0.

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