四(三氟甲基)錫
四(三氟甲基)錫 | |
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識別 | |
CAS號 | 41268-44-4 ![]() |
性質 | |
化學式 | C4F12Sn |
摩爾質量 | 394.73 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
四(三氟甲基)錫是一種有機錫化合物,化學式為Sn(CF3)4。它可由四碘化錫和六氟乙烷在電漿體裝置中反應製得,[1]或由(CF3)2Cd(glyme)(glyme=乙二醇二甲醚)和四碘化錫反應得到。[2]它在三氯甲烷中可以和四苯基錫反應,得到苯基三(三氟甲基)錫[3];它在100 °C分解,生成Sn(CF3)3F。[4]
參考文獻
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- ^ Krause, Larry J.; Morrison, John A. Bis(trifluoromethyl)cadmium·glyme (glyme = dimethoxyethane), a new, powerful fluoroalkylating agent and low-temperature source of difluorocarbene. J. Chem. Soc., Chem. Commun. (Royal Society of Chemistry (RSC)). 1980, (14): 671–672. ISSN 0022-4936. doi:10.1039/c39800000671.
- ^ Eujen, R.; Jahn, N. Dismutierungsreaktionen der trifluormethyl(halogen)stannane, (CF3)nSnX4-n (X = Cl, Br, I). Journal of Fluorine Chemistry (Elsevier BV). 1995, 71 (1): 75–79. ISSN 0022-1139. doi:10.1016/0022-1139(94)03156-t (德語).
- ^ Eujen, R.; Thurmann, U. Preparation and spectroscopic properties of halo(trifluormethyl)stannanes, (CF3)nSnX4-n(德文). Journal of Organometallic Chemistry (1992), 433(1-2), 63-77. ISSN 0022-328X