三均三甲苯基铱

三均三甲苯基铱
别名	三(2,4,6-三甲苯基)铱
识别
CAS号
PubChem	71346054
ChemSpider	28688627
SMILES	CC(C=C(C)C1)=C(C=1C)[Ir](C(C(C)=CC1C)=C(C=1)C)C(C(C)=CC1C)=C(C=1)C;
性质
化学式	C27H33Ir
摩尔质量	549.77 g·mol−1
外观	红棕色晶体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三均三甲苯基铱是一种红棕色的铱(III)配合物，化学式为Ir(C₉H₁₁)₃，可简写为Ir(mes)₃。它最初于1992年通过铑类似物Rh(mes)₃相应的方法制得，^[1]^[2]即格氏试剂MesMgBr和IrCl₃(tht)（tht = 四氢噻吩）在乙醚中的反应。它可溶于己烷、甲苯和六甲基二硅氧烷。它对空气十分敏感，在室温分解。^[1]

参考文献

^ ^1.0 ^1.1 Hay-Motherwell, Robyn S.; Wilkinson, Geoffrey; Hussain-Bates, Bilquis; Hursthouse, Michael B. Homoleptic mesityls of iridium(III,IV,V) and ruthenium(IV,V). Journal of the Chemical Society, Dalton Transactions. 1992-01-01, (24): 3477–3482. ISSN 1364-5447. doi:10.1039/DT9920003477 （英语）.
^ Hay-Motherwell, Robyn S.; Koschmieder, Stefan U.; Wilkinson, Geoffrey; Hussain-Bates, Bilquis; Hursthouse, Michael B. Aryl compounds of rhodium: syntheses and X-ray crystal structures. Journal of the Chemical Society, Dalton Transactions. 1991-01-01, (11): 2821–2830. ISSN 1364-5447. doi:10.1039/DT9910002821 （英语）.

[:4-1] 1.0 ^1.1 Hay-Motherwell, Robyn S.; Wilkinson, Geoffrey; Hussain-Bates, Bilquis; Hursthouse, Michael B. Homoleptic mesityls of iridium(III,IV,V) and ruthenium(IV,V). Journal of the Chemical Society, Dalton Transactions. 1992-01-01, (24): 3477–3482. ISSN 1364-5447. doi:10.1039/DT9920003477 （英语）.

[2] Hay-Motherwell, Robyn S.; Koschmieder, Stefan U.; Wilkinson, Geoffrey; Hussain-Bates, Bilquis; Hursthouse, Michael B. Aryl compounds of rhodium: syntheses and X-ray crystal structures. Journal of the Chemical Society, Dalton Transactions. 1991-01-01, (11): 2821–2830. ISSN 1364-5447. doi:10.1039/DT9910002821 （英语）.

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