二甲基二硫代氨基甲酸亚铁
二甲基二硫代氨基甲酸亚铁 | |
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识别 | |
CAS号 | 15339-38-5 ![]() |
性质 | |
化学式 | C6H12FeN2S4 |
摩尔质量 | 296.28 g·mol−1 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
二甲基二硫代氨基甲酸亚铁是一种化合物,化学式为Fe(S2CNMe2)2。它可由乙酸亚铁和二甲基二硫代氨基甲酸钾在乙醇溶液中反应,过滤产生的沉淀,干燥制得。它在含油酸的十八胺中于180 °C分解,可以得到Fe9S10。[1](η5-C5H5)(CO)3WS2CNMe2和Fe2(CO)9在光照下反应,也会有Fe(S2CNMe2)2生成。[2]
参考文献
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. PMID 29570612. doi:10.3390/nano8040187. (原始内容存档于2018-07-06) (英语). (页面存档备份,存于互联网档案馆)
- ^ Pradeep Mathur, B.H.S. Thimmappa. Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species. Inorganica Chimica Acta. 1988-08, 148 (1): 119–122 [2021-01-06]. doi:10.1016/S0020-1693(00)86021-1. (原始内容存档于2018-06-19) (英语). (页面存档备份,存于互联网档案馆)
拓展阅读
- Oliver A. Ileperuma, Robert D. Feltham. Iron-sulfur complexes of nitric oxide. 2. Synthesis and exchange studies of Fe(NO)X[S2CN(CH3)2]2. Crystal and molecular structure of cis-bis(diethyldithiocarbamato)(nitro)nitrosyliron. Inorganic Chemistry. 1977-08, 16 (8): 1876–1883 [2021-01-06]. ISSN 0020-1669. doi:10.1021/ic50174a011 (英语).
- Lenz, John; Paulus, Albert O.; Bald, John G. Systemic fungicides for control of some diseases of easter lilies. California Agriculture, 1971. 25 (3): 4-5. ISSN: 0008-0845.