六氟磷酸亚硝酰
六氟磷酸亚硝酰 | |
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识别 | |
CAS号 | 16921-91-8 ![]() |
性质 | |
化学式 | F6NOP |
摩尔质量 | 174.97 g·mol−1 |
相关物质 | |
其他阴离子 | 四氟硼酸亚硝酰 |
其他阳离子 | 六氟磷酸硝酰 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
六氟磷酸亚硝酰是一种无机化合物,化学式为NOPF6。它可由亚硝酰氯、氟化氢和五氟化磷在二氧化硫或硝基甲烷中反应制得。[1]它在硝基甲烷中和铜反应,可以得到[Cu(CH3NO2)5(NO)][PF6]2。[2]它在合成中常用作单电子氧化剂。[3]
参考文献
- ^ Stephen J. Kuhn. Nitronium and nitrosonium salts. III. Preparation of nitronium and nitrosonium salts by the interaction of nitryl and nitrosyl chloride with anhydrous HF and Lewis acid fluorides. Canadian Journal of Chemistry. 1967-12-15, 45 (24): 3207–3209 [2023-03-06]. ISSN 0008-4042. doi:10.1139/v67-517 (英语).
- ^ Ashley M. Wright, Guang Wu, Trevor W. Hayton. Structural Characterization of a Copper Nitrosyl Complex with a {CuNO} 10 Configuration. Journal of the American Chemical Society. 2010-10-20, 132 (41): 14336–14337 [2023-03-06]. ISSN 0002-7863. doi:10.1021/ja105930b. (原始内容存档于2023-03-06) (英语).
- ^ Atiya T. Overton, José M. López-de-Luzuriaga, M. Elena Olmos, Ahmed A. Mohamed. Oxidative Rearrangement in Gold Organometallics. Organometallics. 2012-05-14, 31 (9): 3460–3462 [2023-03-06]. ISSN 0276-7333. doi:10.1021/om3001422. (原始内容存档于2023-03-06) (英语).
拓展阅读
- R. D. Peacock, I. L. Wilson. Reactions of oxides of nitrogen with the Group V pentafluorides and stannic fluoride. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1969: 2030 [2023-03-06]. ISSN 0022-4944. doi:10.1039/j19690002030 (英语).
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