氯三溴甲烷

氯三溴甲烷
识别
CAS号	594-15-0
性质
化学式	CBr3Cl
摩尔质量	287.18 g·mol−1
熔点	54 °C（327 K）
沸点	55 °C（328 K）（18 mmHg）; 158.5 °C（431.6 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氯三溴甲烷是一种有机化合物，化学式为CBr₃Cl。它与烯烃反应，以溴和氯二溴甲基加成。^[3]^[4]

制备

氯三溴甲烷可由四氯化碳和三溴化铝回流反应得到，^[1]或通过氯代环己烷和四溴化碳在三溴化铁的催化下反应制得。^[5]

{\ce {CCl4 + AlBr3 -> CBr3Cl + AlCl3}}

{\ce {CBr4 + C6H11Cl -> CBr3Cl + C6H11Br}}

二溴甲醛肟和氯化汞水溶液反应，再和溴、乙酸钠反应，得到亚硝基氯二溴甲烷，再与溴回流反应，也能得到氯三溴甲烷。^[6]

参考文献

^ ^1.0 ^1.1 ^1.2 Ryuichi Tanaka, Shì-Qín Zhèng, Kenji Kawaguchi, Takehide Tanaka. Nucleophilic attack on halogeno(phenyl)acetylenes by halide ions. J. Chem. Soc., Perkin Trans. 2. 1980, (11): 1714–1720 [2021-11-02]. ISSN 0300-9580. doi:10.1039/P29800001714 （英语）.
^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-11-02].
^ Bo Chen, Cheng Fang, Peng Liu, Joseph M. Ready. Rhodium-Catalyzed Enantioselective Radical Addition of CX 4 Reagents to Olefins. Angewandte Chemie International Edition. 2017-07-17, 56 (30): 8780–8784 [2021-11-02]. PMC 5672916 . PMID 28544237. doi:10.1002/anie.201704074. （原始内容存档于2021-11-05）（英语）.
^ Vasil'eva, T. T.; Dostovalova, V. I.; Germanova, L. F.; Nelyubin, B. V. Radical addition of polyhalomethanes to olefins and dienes. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1984. 1810-1814. ISSN 0002-3353.
^ K. B. Yoon, J. K. Kochi. Catalytic bromide and iodide exchange of alkyl chlorides with hydrogen bromide and hydrogen iodide. The Journal of Organic Chemistry. 1989-06, 54 (13): 3028–3036 [2021-11-02]. ISSN 0022-3263. doi:10.1021/jo00274a013. （原始内容存档于2021-11-05）（英语）.
^ Katritzky, A.R.; Gilchrist, T.L.; Meth-Cohn, O.; Rees, C.W. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations. Elsevier Science. 1995: 222 [2021-11-02]. ISBN 978-0-08-042704-1. （原始内容存档于2021-11-04）. |issue=被忽略 (帮助)

[tanaka-1] 1.0 ^1.1 ^1.2 Ryuichi Tanaka, Shì-Qín Zhèng, Kenji Kawaguchi, Takehide Tanaka. Nucleophilic attack on halogeno(phenyl)acetylenes by halide ions. J. Chem. Soc., Perkin Trans. 2. 1980, (11): 1714–1720 [2021-11-02]. ISSN 0300-9580. doi:10.1039/P29800001714 （英语）.

[2] "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-11-02].

[3] Bo Chen, Cheng Fang, Peng Liu, Joseph M. Ready. Rhodium-Catalyzed Enantioselective Radical Addition of CX 4 Reagents to Olefins. Angewandte Chemie International Edition. 2017-07-17, 56 (30): 8780–8784 [2021-11-02]. PMC 5672916 . PMID 28544237. doi:10.1002/anie.201704074. （原始内容存档于2021-11-05）（英语）.

[4] Vasil'eva, T. T.; Dostovalova, V. I.; Germanova, L. F.; Nelyubin, B. V. Radical addition of polyhalomethanes to olefins and dienes. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1984. 1810-1814. ISSN 0002-3353.

[5] K. B. Yoon, J. K. Kochi. Catalytic bromide and iodide exchange of alkyl chlorides with hydrogen bromide and hydrogen iodide. The Journal of Organic Chemistry. 1989-06, 54 (13): 3028–3036 [2021-11-02]. ISSN 0022-3263. doi:10.1021/jo00274a013. （原始内容存档于2021-11-05）（英语）.

[6] Katritzky, A.R.; Gilchrist, T.L.; Meth-Cohn, O.; Rees, C.W. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations. Elsevier Science. 1995: 222 [2021-11-02]. ISBN 978-0-08-042704-1. （原始内容存档于2021-11-04）. |issue=被忽略 (帮助)

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