烟碱烯
烟碱烯 | |
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IUPAC名 3-(1-methylpyrrol-2-yl)pyridine | |
别名 | 二烯烟碱 尼古提林 β-烟碱烯 1-甲基-2-(3-吡啶基)吡咯 3-(1-甲基-2-吡咯基)吡啶 |
识别 | |
CAS号 | 487-19-4 ![]() |
PubChem | 10249 |
ChemSpider | 2282468 |
SMILES |
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ChEBI | 7564 |
KEGG | C10161 |
性质 | |
化学式 | C10H10N2 |
摩尔质量 | 158.2 g·mol−1 |
熔点 | 168—169 °C(441—442 K)[1] |
沸点 | 281 °C(554 K)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
烟碱烯是一种有机化合物,化学式为C10H10N2。它可由烟碱的催化脱氢反应制得;[3]1-甲基吡咯和3-溴吡啶在二异丙基乙胺存在下、9,10-二氰基蒽的催化下于乙腈中反应,也能得到产物。[4]
参见
参考文献
- ^ Spath, Ernst; Tobacco alkaloids. XIII. New tobacco bases. Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen, 1937. 70B: 2450-2454. ISSN: 0365-9488.
- ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-08-14].
- ^ Makoto Shibagaki, Kyoko Takahashi, Hideyuki Kuno, Hajime Matsushita. Preparation of Nicotyrine via Catalytic Dehydrogenation of Nicotine. Agricultural and Biological Chemistry. 1988-10, 52 (10): 2651–2652 [2021-08-14]. ISSN 0002-1369. doi:10.1080/00021369.1988.10869102 (英语).
- ^ Michael Neumeier, Diego Sampedro, Michal Májek, Víctor A. de la Peña O'Shea, Axel Jacobi von Wangelin, Raúl Pérez-Ruiz. Dichromatic Photocatalytic Substitutions of Aryl Halides with a Small Organic Dye. Chemistry - A European Journal. 2018-01-02, 24 (1): 105–108 [2021-08-14]. doi:10.1002/chem.201705326 (英语).