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4,4'-偶氮吡啶

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4,4'-偶氮吡啶
识别
CAS号 2632-99-7  checkY
性质
化学式 C10H8N4
摩尔质量 184.2 g·mol−1
外观 橙色针状晶体
熔点 107—108 °C(380—381 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

4,4'-偶氮吡啶是一种有机化合物,化学式为C10H8N4。它可由4-氨基吡啶和10%次氯酸钠溶液反应制得,[1]或由1,2-二(4-吡啶基)肼和氧气DMF中于80 °C反应得到。[2]它和氰化镍甲苯中回流反应,可以得到四氰合镍(II)酸(4,4'-偶氮吡啶)合镍(II)。[3]它和五羰基氯化铼四氢呋喃/甲苯中回流反应,可以得到三羰基(4,4'-偶氮吡啶)氯化铼四聚体。[4]

参考文献

  1. ^ 1.0 1.1 Jean Pierre Launay, Myriam Tourrel-Pagis, Jean Francois Lipskier, Valerie Marvaud, Christian Joachim. Control of intramolecular electron transfer by a chemical reaction. The 4,4'-azopyridine/1,2-bis(4-pyridyl)hydrazine system. Inorganic Chemistry. 1991-03, 30 (5): 1033–1038 [2022-11-07]. ISSN 0020-1669. doi:10.1021/ic00005a029. (原始内容存档于2022-11-07) (英语). 
  2. ^ Yu Lin, Hao Wu, Ziang Liu, Jin Li, Rui Cai, Makoto Hashimoto, Lei Wang. Additive-free aerobic oxidation of hydroazobenzenes: Access to azobenzenes and epoxidation of enones. Tetrahedron Letters. 2022-10, 108: 154132 [2022-11-07]. doi:10.1016/j.tetlet.2022.154132 (英语). 
  3. ^ Jeffrey T. Culp, Catherine Madden, Kristi Kauffman, Fan Shi, Christopher Matranga. Screening Hofmann Compounds as CO 2 Sorbents: Nontraditional Synthetic Route to Over 40 Different Pore-Functionalized and Flexible Pillared Cyanonickelates. Inorganic Chemistry. 2013-04-15, 52 (8): 4205–4216 [2022-11-07]. ISSN 0020-1669. doi:10.1021/ic301893p. (原始内容存档于2022-11-07) (英语). 
  4. ^ Shih-Sheng Sun, Alistair J. Lees. Self-Assembly Triangular and Square Rhenium(I) Tricarbonyl Complexes: A Comprehensive Study of Their Preparation, Electrochemistry, Photophysics, Photochemistry, and Host−Guest Properties. Journal of the American Chemical Society. 2000-09-01, 122 (37): 8956–8967 [2022-11-07]. ISSN 0002-7863. doi:10.1021/ja001677p. (原始内容存档于2022-11-07) (英语).