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4-二甲氨基苯硫酚

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4-二甲氨基苯硫酚
识别
CAS号 4946-22-9  checkY
性质
化学式 C8H11NS
摩尔质量 153.24 g·mol−1
外观 浅黄色固体[1]
熔点 32 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

4-二甲氨基苯硫酚是一种硫酚类有机化合物,化学式为C8H11NS。它可由硫氰酸(4-二甲氨基苯酯)的还原反应制得。[2][3]它可以被过氧化氢氧化,生成二(4-二甲氨基苯基)二硫化物。[4]

参考文献

  1. ^ 1.0 1.1 Christopher S. Argyle and G. Malcolm Dyson. The constitution and reactions of thiocarbonyl tetrachloride. Part IV. Reaction with secondary and tertiary amines. Journal of the Chemical Society (Resumed). 1937, 1629-1634. doi:10.1039/JR9370001629.
  2. ^ Gal Segalovich-Gerendash, Illya Rozenberg, Nebal Alassad, Noy B. Nechmad, Israel Goldberg, Sebastian Kozuch, and N. Gabriel Lemcoff. mposing Latency in Ruthenium Sulfoxide-Chelated Benzylidenes: Expanding Opportunities for Thermal and Photoactivation in Olefin Metathesis. ACS Catal. 2020, 10, 8, 4827–4834. doi:10.1021/acscatal.0c00676
  3. ^ David E. Bergbreiter, Jonathon D. Frels, Jeffrey Rawson, Jun Li, Joseph H. Reibenspies. Synthesis and characterization of electronically varied XCX palladacycles with functional arene groups. Inorg. Chim. Acta. 2006. 359 (6). 1912-1922. doi:10.1016/j.ica.2005.09.030.
  4. ^ Glen G. Briand, Reagan J. Davidson, and Andreas Decken. Substituent Effects on Indium−Phosphorus Bonding in (4-RC6H4S)3In·PR'3 Adducts (R = H, Me, F; R' = Et, Cy, Ph): A Spectroscopic, Structural, and Thermal Decomposition Study. Inorg. Chem. 2005, 44, 26, 9914–9920. doi:10.1021/ic051138r.