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一锗化钠

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一锗化钠
识别
CAS号 12265-93-9  checkY
性质
化学式 NaGe
摩尔质量 95.63 g·mol⁻¹
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

一锗化钠是一种无机化合物,化学式为NaGe。它可由氢化钠粉反应制得。[1]它和氯化亚铜溴化铵四氯化锗反应,可以得到金属锗。[2][3]它和四锗化十七锂加热,可以得到红色的Li3NaGe2,其中含有[Ge2]4−[4]

它在电化学领域有所研究。[5]

参考文献

  1. ^ Xuchu Ma, Fengyi Wu, Susan M. Kauzlarich. Alkyl-terminated crystalline Ge nanoparticles prepared from NaGe: Synthesis, functionalization and optical properties. Journal of Solid State Chemistry. 2008-07, 181 (7): 1628–1633 [2022-11-12]. doi:10.1016/j.jssc.2008.06.018. (原始内容存档于2022-06-18) (英语). 
  2. ^ Paul F. McMillan, Jan Gryko, Craig Bull, Richard Arledge, Anthony J. Kenyon, Barbara A. Cressey. Amorphous and nanocrystalline luminescent Si and Ge obtained via a solid-state chemical metathesis synthesis route. Journal of Solid State Chemistry. 2005-03, 178 (3): 937–949 [2022-11-12]. doi:10.1016/j.jssc.2004.12.040. (原始内容存档于2022-06-18) (英语). 
  3. ^ Boyd R Taylor, Glenn A Fox, Lousia J Hope-Weeks, Robert S Maxwell, Susan M Kauzlarich, Howard W.H Lee. Solution preparation of Ge nanoparticles with chemically tailored surfaces. Materials Science and Engineering: B. 2002-11, 96 (2): 90–93 [2022-11-12]. doi:10.1016/S0921-5107(02)00297-0. (原始内容存档于2018-07-03) (英语). 
  4. ^ Lavinia M. Scherf, Antti J. Karttunen, Oliver Pecher, Pieter C. M. M. Magusin, Clare P. Grey, Thomas F. Fässler. [Ge 2 ] 4− Dumbbells with Very Short Ge−Ge Distances in the Zintl Phase Li 3 NaGe 2 : A Solid-State Equivalent to Molecular O 2. Angewandte Chemie International Edition. 2016-01-18, 55 (3): 1075–1079 [2022-11-12]. doi:10.1002/anie.201508044. (原始内容存档于2022-11-12) (英语). 
  5. ^ T. Kajita, T. Itoh. Electrochemical performance of highly amorphous GeO x powders synthesized in different alcohols for use in Na- and Li-ion batteries. RSC Advances. 2016, 6 (104): 102109–102115 [2022-11-12]. ISSN 2046-2069. doi:10.1039/C6RA20794D (英语).