1H-硼杂苯
1H-硼杂苯 | |
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英文名 | boratabenzene |
识别 | |
CAS号 | 55926-39-1 ![]() |
SMILES |
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性质 | |
化学式 | C5H6B− |
摩尔质量 | 76.91 g·mol⁻¹ |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
![](http://images.weserv.nl/?url=//upload.wikimedia.org/wikipedia/commons/thumb/0/00/Structure_of_Rh%28C8H12%29%28C5H5BH%29_%28OZUFAR%29.png/220px-Structure_of_Rh%28C8H12%29%28C5H5BH%29_%28OZUFAR%29.png)
1H-硼杂苯是一种杂环阴离子,化学式为[C5H5BH]-。它和环戊二烯阴离子相似,可以形成夹心或半夹心的过渡金属配合物。[2][3]硼杂苯和吡啶的加合物C5H5B·py具有和1H-硼杂苯相似的性质,其结构可用C5H5B--N+C5H5表示。
参考文献
- ^ Yuan, Yuanyuan; Wang, Xiufang; Li, Yuxue; Fan, Liyan; Xu, Xin; Chen, Yaofeng; Li, Guangyu; Xia, Wei. Rapid Entry to Functionalized Boratabenzene Complexes through Metal-Induced Hydroboration at the Anionic 1-H-Boratabenzene Ligand. Organometallics. 2011, 30 (16): 4330–4341. doi:10.1021/om200396k.
- ^ Janiak, Christoph. Metallocene and Related Catalysts for Olefin, Alkyne and Silane Dimerization and Oligomerization. Coordination Chemistry Reviews. 2006, 250 (1–2): 66–94. doi:10.1016/j.ccr.2005.02.016.
- ^ Cui, Peng; Chen, Yaofeng. Boratabenzene Rare-earth Metal Complexes. Coordination Chemistry Reviews. 2016, 314: 2–13. doi:10.1016/j.ccr.2015.07.014.