獼猴桃鹼
獼猴桃鹼 | |
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IUPAC名 (7S)-4,7-Dimethyl-6,7-dihydro-5H-cyclopenta[c]pyridine | |
識別 | |
CAS號 | 524-03-8 ![]() |
PubChem | 68231 |
ChemSpider | 61533 |
SMILES |
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InChI |
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InChIKey | ZHQQRIUYLMXDPP-ZETCQYMHBZ |
Beilstein | 81308 |
ChEBI | 2443 |
KEGG | C09910 |
性質 | |
化學式 | C10H13N |
摩爾質量 | 147.22 g·mol−1 |
熔點 | 25 °C(298 K) |
沸點 | 100 - 103 °C(270 K) |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
獼猴桃鹼(英語:Actinidine)是一種環烯醚萜化合物,由多種植物和動物在自然界中產生。它是第一個被發現的環戊單萜生物鹼。[1]它是可從纈草(Valeriana officinalis)根[2]和葛棗獼猴桃(Actinidia polygama)以及幾種處於幼蟲和成蟲階段的昆蟲中提取的化合物之一。[3]獼猴桃鹼是一種貓引誘劑,其作用類似於貓薄荷中的活性化合物荊芥內酯。[4]
某些竹節蟲物種,包括Megacrania batesii和津田氏大頭䗛(Megacrania tsudai),具有化學防禦機制,當受到捕食者威脅時,其前胸腺會分泌含獼猴桃鹼的物質。[5]
生物合成
參考資料
- ^ Tsutsui, Minoru; Tsutsui, Ethel Ashworth. Diterpenoids. Chemical Reviews. 1959, 59 (6): 1031–1075. doi:10.1021/cr50030a003.
- ^ Janot MM, Guilhem J, Contz O, Venera G, Cionga E. Contribution to the study of valerian alcaloids (Valeriana officinalis L.): actinidine and naphthyridylmethylketone, a new alkaloid. Ann. Pharm. Fr. 1979, 37 (9–10): 413–20. PMID 547813 (法語).
- ^ Weibel DB, Oldham NJ, Feld B, Glombitza G, Dettner K, Boland W. Iridoid biosynthesis in staphylinid rove beetles (Coleoptera: Staphylinidae, Philonthinae). Insect Biochemistry and Molecular Biology. 2001, 31 (6–7): 583–591. PMID 11267897. doi:10.1016/s0965-1748(00)00163-6.
- ^ Lichman, Benjamin R.; Godden, Grant T.; Hamilton, John P.; Palmer, Lira; Kamileen, Mohamed O.; Zhao, Dongyan; Vaillancourt, Brieanne; Wood, Joshua C.; Sun, Miao; Kinser, Taliesin J.; Henry, Laura K. The evolutionary origins of the cat attractant nepetalactone in catnip. Science Advances. 2020-05-01, 6 (20): eaba0721. Bibcode:2020SciA....6..721L. ISSN 2375-2548. PMC 7220310
. PMID 32426505. doi:10.1126/sciadv.aba0721
(英語).
- ^ Wu, I-Hsin; Liu, Hsui-Huei; Chen, Yu-Yen; Tsai, Cheng-Lung; Yu, Yi-Ching; Hsiao, Chung-Yi; Yeh, Wen-Bin. Life cycles, phenology and genetic structure of endangered Megacrania tsudai Shiraki (Phasmatodea: Phasmatidae): Male individuals from a geographic parthenogenesis species. Entomological Science. 2020, 23 (2): 183–192. S2CID 216322536. doi:10.1111/ens.12410.
- ^ Funayama, Shinji; Cordell, Geoffrey A. (編). 14: Alkaloids Derived from Terpenoids. Alkaloids. Academic Press. 2015: 233–255.
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