甲酸錳

甲酸錳是一種甲酸鹽，化學式為Mn(HCOO)₂，或寫作Mn₃(HCOO)₆^[2]。它可由碳酸錳和甲酸水溶液反應得到，從溶液中可以結晶出二水合物。^[3]

MnCO₃ + 2 HCOOH → Mn(HCOO)₂ + H₂O + CO₂↑

它和4,4'-聯吡啶（bpy）在DMF-水中反應，可以得到淺黃色的Mn(HCOO)₂(bpy)。^[4]

參考文獻

^ Osaki, K., Nakai, Y., & Watanabé, T. (1964). The Crystal Structures of Magnesium Formate Dihydrate and Manganous Formate Dihydrate. Journal of the Physical Society of Japan, 19(5), 717–723. doi:10.1143/jpsj.19.717
^ Polyhedron, 2007. 26 (9-11). doi:10.1016/j.poly.2006.10.043
^ Roger C. Eckhardt; Ted B. Flanagan. Anisotropic solid-state reaction. Dehydration of manganous formate dihydrate. Trans. Faraday Soc., 1964,60, 1289-1298. doi:10.1039/TF9646001289.
^ Inorg. Chem. 2005, 44, 3, 572–583. doi:10.1021/ic049170t