三氟甲磺酸鈾酰
三氟甲磺酸鈾酰 | |
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識別 | |
CAS號 | 168915-05-7 ![]() |
性質 | |
化學式 | C2F6O8S2U |
摩爾質量 | 568.17 g·mol−1 |
外觀 | 淺黃色粉末(無水) 亮黃色粉末(水合)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
三氟甲磺酸鈾酰是一種無機化合物,化學式為UO2(CF3SO3)2。它可由三氧化鈾和三氟甲磺酸或三氟甲磺酸酐反應製得。[1]它和雙(環辛四烯)合鈾在吡啶中回流反應,可以得到[U6O8(CF3SO3)8(C5H5N)8]。[2]它和三甲基碘矽烷反應,可以得到碘化鈾酰。[3]
參考文獻
- ^ 1.0 1.1 Berthet, Jean Claude; Lance, Monique; Nierlich, Martine; Ephritikhine, Michel. Simple Preparations of the Anhydrous and Solvent-Free Uranyl and Cerium(IV) Triflates UO2(OTf)2 and Ce(OTf)4 − Crystal Structures of UO2(OTf)2(py)3 and [{UO2(py)4}2(μ-O)][OTf]2. European Journal of Inorganic Chemistry (Wiley). 2000, 2000 (9): 1969–1973. ISSN 1434-1948. doi:10.1002/1099-0682(200009)2000:9<1969::aid-ejic1969>3.0.co;2-0.
- ^ Berthet, Jean-Claude; Thuéry, Pierre; Ephritikhine, Michel. Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η8-C8H8)2] and Uranyl [UO2X2] Compounds. Inorganic Chemistry (American Chemical Society (ACS)). 2010-07-26, 49 (17): 8173–8177. ISSN 0020-1669. doi:10.1021/ic101310z.
- ^ Berthet, Jean-Claude; Nierlich, Martine; Ephritikhine, Michel. Synthesis of the stable UO2I2, the last of the uranyl dihalides. X-Ray crystal structure of [UO2I2(py)3]. Chemical Communications (Royal Society of Chemistry (RSC)). 2004, (7): 870. ISSN 1359-7345. doi:10.1039/b400717d.