六氟化鈈是鈈的最高價氟化物。
它是一種紅棕色的揮發性固體。[1]六氟化鈈的升華熱是12.1 kcal/mol[2],揮發熱則是7.4 kcal/mol。[2]因為它的腐蝕性,六氟化鈈很難運送。[3][4]
它可以由四氟化鈈 (PuF4) 與強氟化劑(如氟單質)化合而成。[2][5][6][7]
- PuF
4 + F
2 → PuF
6
它也可以由氟化三氟化鈈或二氧化鈈而成。[6]
- 2 PuF
3 + 3 F
2 → 2 PuF
6
- PuO
2 + 3 F
2 → PuF
6 + O
2
參考資料
- ^ 1.0 1.1 Lide, David R. Handbook of Chemistry and Physics 90. Boca Raton, Florida: CRC Press. 2009: 4–81. ISBN 978-1-4200-9084-0. (webelements.com (頁面存檔備份,存於互聯網檔案館))
- ^ 2.0 2.1 2.2 Florin, Alan E.; Tannenbaum, Irving R.; Lemons, Joe F. Preparation and properties of plutonium hexafluoride and identification of plutonium(VI) oxyfluoride. Journal of Inorganic and Nuclear Chemistry. 1956, 2 (5–6): 368–379. doi:10.1016/0022-1902(56)80091-2.
- ^ Bibler, Ned E. α and β Radiolysis of Plutonium Hexafluoride Vapor. J. Phys. Chem. August 23, 1979, 83 (17): 2179–2186. doi:10.1021/j100480a001.
- ^ Steindler, M.J.; Steidl, D.V.; Fischer, J. The decomposition of plutonium hexafluoride by gamma radiation. Journal of Inorganic and Nuclear Chemistry. November 1964, 26 (11): 1869–1878. doi:10.1016/0022-1902(64)80011-7.
- ^ A. E. Florin. Plutonium Hexafluoride: Second Report On The Preparation and Properties (LA-1168) (PDF). Los Alamos Scientific Laboratory. 9 November 1950 [2020-04-22]. (原始內容存檔 (PDF)於2016-03-03).
- ^ 6.0 6.1 Mandleberg, C.J.; Rae, H.K.; Hurst, R.; Long, G.; Davies, D.; Francis, K.E. Plutonium hexafluoride. Journal of Inorganic and Nuclear Chemistry. 1956, 2 (5–6): 358–367. doi:10.1016/0022-1902(56)80090-0.
- ^ Weinstock, Bernard; Malm, John G. The properties of plutonium hexafluoride. Journal of Inorganic and Nuclear Chemistry. July 1956, 2 (5–6): 380–394. doi:10.1016/0022-1902(56)80092-4.
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