素馨醛
素馨醛 | |
---|---|
IUPAC名 (2Z)-2-benzylideneheptanal | |
英文名 | Jasminaldehyde |
別名 | 2-亞苄基庚醛 α-戊基肉桂醛 茉莉醛 |
識別 | |
CAS號 | 122-40-7 78605-96-6(2E) 101365-33-7(2Z) |
PubChem | 1712058 |
ChemSpider | 1361549 |
SMILES |
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ChEBI | 32318 |
DrugBank | DB14175 |
KEGG | C12288 |
性質 | |
化學式 | C14H18O |
摩爾質量 | 202.29 g·mol−1 |
危險性 | |
GHS危險性符號 | |
GHS提示詞 | 警告 |
H-術語 | H317, H411 |
P-術語 | P261, P272, P273, P280, P302+352, P321, P333+313, P363, P391, P501 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
素馨醛(英語:Jasminaldehyde)是一種有機化合物,化學式為C14H18O,可用作食品香料。它可由苯甲醛和正庚醛在鹼溶液(如氫氧化鈉水溶液)中反應製得。[1]它在催化下可以被氫氣[2]或三乙氧基矽烷[3]還原,得到2-亞苄基庚醇。
參考文獻
- ^ Manu Vashishtha, Manish Mishra, Dinesh O. Shah. A novel approach for selective cross aldol condensation using reusable NaOH-cationic micellar systems. Applied Catalysis A: General. 2013-09, 466: 38–44 [2021-07-21]. doi:10.1016/j.apcata.2013.06.015 (英語).
- ^ Rongzhou Wang, Yuancheng Yue, Jipeng Qi, Shiyuan Liu, Ao Song, Shuping Zhuo, Ling-Bao Xing. Ambient-pressure highly active hydrogenation of ketones and aldehydes catalyzed by a metal-ligand bifunctional iridium catalyst under base-free conditions in water. Journal of Catalysis. 2021-07, 399: 1–7 [2021-07-21]. ISSN 0021-9517. doi:10.1016/j.jcat.2021.04.023.
- ^ Tingting Zheng, Junye Li, Shumiao Zhang, Benjing Xue, Hongjian Sun, Xiaoyan Li, Olaf Fuhr, Dieter Fenske. Selective C–F and C–H Activation of Fluoroarenes by Fe(PMe3)4 and Catalytic Performance of Iron Hydride in Hydrosilylation of Carbonyl Compounds. Organometallics. 2016-09-30, 35 (20): 3538–3545 [2021-07-21]. ISSN 0276-7333. doi:10.1021/acs.organomet.6b00546.