2,5-環己二烯-1,4-二亞胺
| 2,5-環己二烯-1,4-二亞胺 | |
|---|---|
| |
| 別名 | 對苯醌二亞胺 PDI |
| 識別 | |
| CAS號 | 4377-73-5 
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| SMILES |
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| 性質 | |
| 化學式 | C6H6N2 |
| 摩爾質量 | 106.13 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
2,5-環己二烯-1,4-二亞胺是一種有機化合物，化學式為C6H6N2。它可由對苯二胺經化學[1]或電化學[2]氧化得到：
- H2NC6H4NH2 ⇌ HN=C6H4=NH + 2 H+ + 2 e−
它可以和間苯二酚發生偶合反應，生成4-(4-氨基苯胺基)-1,3-苯二酚。[1]
參考文獻
- ^ 1.0 1.1 Aaron D. Bailey; Bryan P. Murphy; and Hairong Guan. Mechanistic Insights into Oxidative Oligomerization of p-Phenylenediamine and Resorcinol. J. Phys. Chem. A 2016, 120, 43, 8512–8520. doi:10.1021/acs.jpca.6b08571.
- ^ Sarawudh Nathabumroong, Chatwarin Poochai, Johannes Philipp Mensing, Chakrit Sriprachuabwong, Jaruwit Lohitkarn, Tanom Lomas, Rattikorn Yimnirun, and Adisorn Tuantranont. Violet Laser Treatment of Nitrogen-Doped Reduced Graphene Oxide Electrodes and KOH Electrolytes Containing p-Phenylenediamine for High-Performance Supercapacitors. ACS Appl. Nano Mater. 2023, 6, 1, 34–43. doi:10.1021/acsanm.2c03373.
延伸閱讀
- Nobuyuki Akai, Satoshi Kudoh, and Munetaka Nakata. UV Photolysis of 1,4-Diaminobenzene in a Low-Temperature Argon Matrix to 2,5-Cyclohexadiene-1,4-diimine via 4-Aminoanilino Radical. J. Phys. Chem. A 2003, 107, 34, 6725–6730. doi:10.1021/jp022694z.