叠氮化铯

叠氮化铯是一种无机化合物，由铯和氮构成，属于叠氮酸盐、叠氮化合物，其化学式为CsN₃。晶体结构为四方结构，和同族叠氮化合物相似^[5]。在加热或紫外线照射时，它会分解成氮气和金属铯。^[6]^[7]要制备叠氮化铯可将和碳酸铯和叠氮酸的中和反应制备；或胺基铯与一氧化二氮反应而制得；或碳酸铯和叠氮化钠的复分解反应制备，反应式如下:

Cs₂CO₃ + 2HN₃ → 2CsN₃ + H₂CO₃

CsNH₂ + N₂O → CsN₃ + H₂O

Cs₂CO₃ + 2NaN₃ → 2CsN₃ + Na₂CO₃

参考文献

^ ^1.0 ^1.1 Dale L. Perry; Sidney L. Phillips. Handbook of inorganic compounds. CRC Press. 1995: 301. ISBN 0849386713.
^ 来源：Sigma-Aldrich Co., product no. 510181 .
^ Georg Brauer, Handbuch der Präparativen Anorganischen Chemie, Band I, Seite 458. 1975,
ISBN 3-432-02328-6
（德文）
^ Dale L. Perry, Sidney L. Phillips: Handbook of inorganic compounds. CRC Press, 1995, ISBN 978-0-8493-8671-8, S. 333 (叠氮化铯，第333页，载于Google图书).
^ ^5.0 ^5.1 Khilji, M. Y.; Sherman, W. F.; Wilkinson, G. R. Variable temperature and pressure Raman spectra of potassium azide KN3. Journal of Raman Spectroscopy (Wiley-Blackwell). 1982, 12 (3): 300–303. ISSN 0377-0486. doi:10.1002/jrs.1250120319.
^ Tompkins, F. C.; Young, D. A. The Photochemical and Thermal Formation of Colour Centres in Potassium Azide Crystals. Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences. 1982, 236 (1204): 10–23.
^ Pradyot Patnaik. Handbook of inorganic chemicals. McGraw-Hill Professional. 2003: 734. ISBN 0070494398.
^ Pringle, G. E.; Noakes, D. E. The crystal structures of lithium, sodium and strontium azides. Acta Cryst. February 1968,. B24 (2): 262–269. doi:10.1107/S0567740868002062.