三氟合锰(II)酸钾
三氟合锰(II)酸钾 | |
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别名 | 氟化锰钾 |
识别 | |
CAS号 | 13827-01-5 |
性质 | |
化学式 | KMnF3 |
摩尔质量 | 151.03 g·mol⁻¹ |
外观 | 浅粉色固体[1] |
密度 | 3.24 g·cm−3[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
三氟合锰(II)酸钾是一种无机化合物,化学式为KMnF3。它是立方晶系的浅粉色晶体,空间群Pm3m。[3]它可由溴化锰(或氯化锰[2])和氟化钾在甲醇中反应制得。[1]它和氟气反应,可以得到KMnF5。[2]
相关化合物
参考文献
- ^ 1.0 1.1 David S. Crocket, Helmut M. Haendler. Synthesis of Fluorometallates in Methanol. Some Structure Relationships 1a. Journal of the American Chemical Society. 1960-08, 82 (16): 4158–4162 [2021-01-07]. ISSN 0002-7863. doi:10.1021/ja01501a009 (英语).
- ^ 2.0 2.1 2.2 Hoppe, Rudolf; Liebe, Werner; Dahne, Wolfgang. Fluomanganates of the alkali metals. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1961. 307. 276-289.
- ^ Yury Ivanov, Tatsuya Nimura, Kiyoaki Tanaka. Electron density and electrostatic potential of KMnF 3 : a phase-transition study. Acta Crystallographica Section B Structural Science. 2004-08-01, 60 (4): 359–368 [2021-01-07]. ISSN 0108-7681. doi:10.1107/S0108768104009437. (原始内容存档于2018-06-04).
- ^ Cousseins, Jean Claude. Solid-state study of some ternary fluorides; synthesis; identification; relation; miscibility. Rev. Chim. Minerale, 1964. 1 (4): 573-616.
- ^ Chretien, Andre; Cousseins, Jean Claude. Differentiation of the alkali elements by their double manganese fluorides. II. Compt. Rend., 1964. 259 (25): 4649-4699.