异丁酸钠
异丁酸钠 | |
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别名 | 2-甲基丙酸钠 |
识别 | |
CAS号 | 996-30-5 ![]() |
性质 | |
化学式 | C4H7NaO2 |
摩尔质量 | 110.09 g·mol−1 |
外观 | 粉末[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
异丁酸钠是一种羧酸盐,化学式为C4H7NaO2。它可由异丁酸和氢氧化钠反应制得。[1]它和硝酸铁或高氯酸铁反应,可以得到[Fe3O(C4H7O2)6(H2O)3]A(A=ClO4, NO3)。[2]它和硼烷的四氢呋喃溶液反应,可以得到异丁酸硼氢化钠,它经PCC氧化可以得到异丁醛。[3]
参考文献
- ^ 1.0 1.1 Chad E. Davis, Bryan C. Duffy, Robert M. Coates. Total Synthesis of (±)-Cameroonan-7α-ol and Biomimetic Rearrangements to Related Nopsane Sesquiterpenes. The Journal of Organic Chemistry. 2003-09-01, 68 (18): 6935–6943 [2023-02-27]. ISSN 0022-3263. doi:10.1021/jo0343580. (原始内容存档于2023-02-26) (英语).
- ^ Anastasia N. Georgopoulou, Yiannis Sanakis, Vassilis Psycharis, Catherine P. Raptopoulou, Athanassios K. Boudalis. Mössbauer spectra of two extended series of basic iron(III) carboxylates [Fe3O(O2CR)6(H2O)6]A (A− = ClO4 −, NO3 −). Hyperfine Interactions. 2010-06, 198 (1-3): 229–241 [2023-02-27]. ISSN 0304-3843. doi:10.1007/s10751-010-0179-2 (英语).
- ^ Cha J S, Park J H, Mun S J. Transformation of carboxylic acid salts to aldehydes by stepwise reduction with borane and oxidation with pyridinium chlorochromate. Bulletin of the Korean Chemical Society, 2001, 22(10): 1089-1092.
拓展阅读
- Vorlander, D. Behavior of Salts of Organic Acids when Melted. Berichte der Deutschen Chemischen Gesellschaft. 1911, 43: 3120–3135. ISSN 0365-9496..
- George A. Blondin, William J. Vail, David E. Green. The mechanism of mitochondrial swelling. Archives of Biochemistry and Biophysics. 1969-01, 129 (1): 158–172 [2023-02-27]. doi:10.1016/0003-9861(69)90162-3. (原始内容存档于2018-07-01) (英语).