1-十九烷醇
1-十九烷醇 | |
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IUPAC名 nonadecan-1-ol | |
别名 | 1-十九醇 正十九醇 |
识别 | |
CAS号 | 1454-84-8 |
PubChem | 80281 |
ChemSpider | 72522 |
SMILES |
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性质 | |
化学式 | C19H40O |
摩尔质量 | 284.52 g·mol−1 |
熔点 | 59—61 °C(332—334 K)[1] 62—63 °C(335—336 K)[2] |
沸点 | 204—217 °C(477—490 K)(3 torr)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
1-十九烷醇是一种有机化合物,化学式为C19H40O,可由十九酸的还原反应制得。[3]它和溴在三苯基膦催化下反应[4],或和四溴化碳、三苯基膦在二氯甲烷中反应[5],可以得到1-溴十九烷。它和对甲苯磺酰氯反应,生成相应的酯。[6]
参考文献
- ^ 1.0 1.1 James Cason, Helen J. Wolfhagen, Winifred Tarpey, Raylene E. Adams. BRANCHED-CHAIN FATTY ACIDS. X. SYNTHESIS OF ACIDS WITH BRANCHING METHYL GROUPS NEAR THE CARBOXYL. The Journal of Organic Chemistry. 1949-01, 14 (1): 147–154 [2021-03-17]. ISSN 0022-3263. doi:10.1021/jo01153a021 (英语).
- ^ Scholl, A. W.; Morrison, J. G. Preparation and properties of n-nonadecyl and n-eicosyl formates. West Va. Univ. Bull., Proc. West Va. Acad. Sci., 1955. V1954. 26: 35-37. CAN50: 44260.
- ^ Juma'a R. Al Dulayymi, Mark S. Baird, Evan Roberts. The synthesis of a single enantiomer of a major α-mycolic acid of M. tuberculosis. Tetrahedron. 2005-12, 61 (50): 11939–11951 [2021-03-17]. doi:10.1016/j.tet.2005.09.056. (原始内容存档于2018-07-02) (英语).
- ^ Oldřich Kocián, Karel Stránský, Jiří Závada. Unsaturated analogues of 1-triacontanol. Collection of Czechoslovak Chemical Communications. 1982, 47 (5): 1346–1355 [2021-03-17]. ISSN 0010-0765. doi:10.1135/cccc19821346. (原始内容存档于2018-06-05) (英语).
- ^ Yasuhisa Yamamura, Yuri Nakazawa, Shoichi Kutsumizu, Kazuya Saito. Molecular packing in two bicontinuous Ia 3̄ d gyroid phases of calamitic cubic mesogens BABH( n ): roles in structural stability and reentrant behavior. Physical Chemistry Chemical Physics. 2019, 21 (42): 23705–23712 [2021-03-17]. ISSN 1463-9076. doi:10.1039/C9CP04424H (英语).
- ^ Kaoru Marukawa, Hirosato Takikawa, Kenji Mori. Synthesis of the Enantiomers of Some Methyl-branched Cuticular Hydrocarbons of the Ant, Diacamma sp.. Bioscience, Biotechnology, and Biochemistry. 2001-01, 65 (2): 305–314 [2021-03-17]. ISSN 0916-8451. doi:10.1271/bbb.65.305. (原始内容存档于2022-01-21) (英语).