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一氯化铟

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一氯化铟
识别
CAS号 13465-10-6  checkY
性质
外观 红色或黄色
密度 4.218 g/cm3[1]
熔点 216 °C(489 K)
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

一氯化铟是一种无机化合物,化学式为InCl,它在120 °C以下为黄色的立方晶型,在此温度之上为红色的正交晶型。[2]它可由三氯化铟反应制得。[3][4]它和三氟甲磺酸在甲苯中反应,可以得到三氟甲磺酸铟(I)。[5]

参考文献

  1. ^ Van Den Berg, J. M. The crystal structure of the room temperature modification of indium chloride, InCl. Acta Crystallographica. 1966, 20 (6): 905–910. Bibcode:1966AcCry..20..905V. doi:10.1107/S0365110X66002032. 
  2. ^ Pardoe, Jennifer A. J.; Downs, Anthony J. Development of the Chemistry of Indium in Formal Oxidation States Lower than +3. Chemical Reviews. 2007-01-01, 107 (1): 2–45 [2024-01-09]. ISSN 0009-2665. PMID 17212469. doi:10.1021/cr068027+. (原始内容存档于2024-01-07) (英语). 
  3. ^ Annan, Theodore A.; Chadha, Raj K.; Doan, Peter; McConville, David H.; McGarvey, Bruce R.; Ozarowski, Andrzej; Tuck, Dennis G. One-electron transfer processes in the reaction of indium(I) halides with substituted o-quinones. Inorganic Chemistry. October 1990, 29 (20): 3936–3943 [2024-01-09]. ISSN 0020-1669. doi:10.1021/ic00345a007. (原始内容存档于2024-01-07) (英语). 
  4. ^ Poland, J. S.; Tuck, D. G. Coordination compounds of indium: XIV. The insertion of indium(I) iodide into carbon-iodide bonds. Journal of Organometallic Chemistry. 1972-09-01, 42 (2): 315–323. ISSN 0022-328X. doi:10.1016/S0022-328X(00)90080-9. 
  5. ^ Indium(i) trifluoromethanesulfonate and other soluble salts for univalent indium chemistry. Chem Commun. 2004. 250-251. doi:10.1039/B312983G.