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六氟磷酸銅

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六氟磷酸銅

英文名 Copper(II) hexafluorophosphate
識別
CAS號 117288-37-6  checkY
性質
化學式 Cu(PF6)2
摩爾質量 353.47 g·mol⁻¹
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

六氟磷酸銅是一種無機化合物,化學式為Cu(PF6)2,其中PF6為非配位陰離子[1]

製備

六氟磷酸銅可由硝酸銅六氟磷酸銨按1:2化學計量比反應得到。[2]

Cu(NO3)2 + 2 NH4PF6 → Cu(PF6)2 + 2 NH4NO3

配合物

六氟磷酸銅可以形成配合物[Cu(L)2ONC(CN)2]PF6(L=鄰二氮菲2,2'-聯吡啶)。[3]

參考文獻

  1. ^ Honeychuck, R. V.; Hersh, W. H. Coordination of "Noncoordinating" Anions: Synthesis, Characterization, and X-ray Crystal Structures of Fluorine-Bridged [SbF6], [BF4], and [PF6] Adducts of [R3P(CO)3(NO)W]+. An Unconventional Order of Anion Donor Strength. Inorganic Chemistry. 1989, 28 (14): 2869–2886. doi:10.1021/ic00313a034. 
  2. ^ G Mukherjee,K Biradha. Coordination Polymers Containing M2L2 and M4L4 Metallacylces of Bis(pyridylcarboxamido)alkanes with an Odd Number of −(CH2)– Groups as Spacers: Guest Inclusion and Networks Recognition via α Sheet. Crystal Growth & Design, 2013, 13(9):4100–4109
  3. ^ Potocnak, I.; Vavra, M.; Jager, L.; et al. Ligand rigidity and the shape of the coordination polyhedra in five-coordinated copper(II) complexes with nitrosodicyanmethanide. Monograph Series of the International Conferences on Coordination Chemistry held periodically at Smolenice in Slovakia (2005)7, 306-312

拓展閱讀

  • AF Clifford,HC Beachell,WM Jack. The hydrogen fluoride solvent system—I A qualitative survey of acids. Journal of Inorganic & Nuclear Chemistry, 1957, 5(1):57-70